Two electrically different molecular conductors based on unsymmetrical Au(III)-Dithiolene complexes with similar crystal structures

Kazuya Kubo, Akiko Nakao, Yasuyuki Ishii, Masafumi Tamura, Reizo Kato, Gen Etsu Matsubayashi

研究成果: Article

2 引用 (Scopus)

抜粋

The cation radical salt based on unsymmetrical metal-dithiolene complexes [Au(ppy)(C 8H 4S 8)] 2[PF 6] (1) is a semiconductor with small activation energy under ambient pressure, and shows metallic behavior under high pressure. On the other hand, [Au(ppy)(C 8H 4 S 6O 2)] 2[BF 4] (2) is an insulator in spite of the structural similarity. Effective conduction pathways through the S⋯S contacts were found in the crystal structure of 1. However, the crystal of 2 contains no such conduction pathways. Comparison of the energy band structures of 1 and 2 suggests that even a subtle difference in cation arrangements makes a remarkable difference between the electrical properties of 1 and 2.

元の言語English
ページ(範囲)417-420
ページ数4
ジャーナルJournal of Low Temperature Physics
142
発行部数3-4
DOI
出版物ステータスPublished - 2006 2 1
外部発表Yes

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Materials Science(all)
  • Condensed Matter Physics

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