Ultramacrocyclization through reversible catenation

Akiko Hori, Tomohisa Sawada, Ken Ichi Yamashita, Makoto Fujita

研究成果: Article査読

31 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Extreme macrocyclization! An ultramacrocyclic structure with 238 non-hydrogen atoms in its backbone is obtained quantitatively through the reversible catenation of a double-loop compound that contains PdII-clipped coordination rings at both ends (see structure). The PdII ring can be regarded as a nanoscale reaction center that is available for connecting nano-scopic components without high entropy costs.

本文言語English
ページ(範囲)4896-4899
ページ数4
ジャーナルAngewandte Chemie - International Edition
44
31
DOI
出版ステータスPublished - 2005 8 5
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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