Ultramacrocyclization through reversible catenation

Akiko Hori; Tomohisa Sawada; Ken Ichi Yamashita; Makoto Fujita

doi:10.1002/anie.200501559

Ultramacrocyclization through reversible catenation

Akiko Hori, Tomohisa Sawada, Ken Ichi Yamashita, Makoto Fujita

研究成果: Article › 査読

34 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Extreme macrocyclization! An ultramacrocyclic structure with 238 non-hydrogen atoms in its backbone is obtained quantitatively through the reversible catenation of a double-loop compound that contains Pd^II-clipped coordination rings at both ends (see structure). The Pd^II ring can be regarded as a nanoscale reaction center that is available for connecting nano-scopic components without high entropy costs.

本文言語	English
ページ（範囲）	4896-4899
ページ数	4
ジャーナル	Angewandte Chemie - International Edition
巻	44
号	31
DOI	https://doi.org/10.1002/anie.200501559
出版ステータス	Published - 2005 8月 5
外部発表	はい

ASJC Scopus subject areas

触媒
化学 (全般)

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10.1002/anie.200501559

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keywords = "Catenanes, Molecular recognition, Palladium, Self-assembly, Supramolecular chemistry",

author = "Akiko Hori and Tomohisa Sawada and Yamashita, {Ken Ichi} and Makoto Fujita",

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AU - Yamashita, Ken Ichi

AU - Fujita, Makoto

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KW - Molecular recognition

KW - Palladium

KW - Self-assembly

KW - Supramolecular chemistry

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Ultramacrocyclization through reversible catenation

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